
You can use the computer model below to explore how the starting concentration of dinitrogen pentoxide, N_{2}O_{5}, affects the inital rate of the reaction:
Make a measurement of initial rate of reaction (i.e. at time = 0 seconds) for various starting concentrations of nitrogen pentoxide, [N_{2}O_{5}]. The model is set to work at a temperature of 338K.
Carry out the following steps: (Model)
Back to instructions.
You should have found that there is a straight line relationship between the initial rate of reaction and the starting concentration of reactant. You should have found that the straight line has a gradient of about 5.2 x 10^{3} s^{1}.
This can be more generally expressed as saying there is a linear relationship between the rate of reaction and the reactant concentration. Mathematically this is:
rate of reaction is proportional to the reactant concentration In the case you have been studying:
rate[N_{2}O_{5}]
or
rate = k[N_{2}O_{5}] where k is the constant of proportionality, commonly called the rate constant, with units in this case of s^{1} and the equation relating rate to concentration is known as a rate expression.
The value of the rate constant varies with the temperature, so the value of k = 5.2 x 10^{3}s^{1} for the decomposition of dinitrogen pentoxide is specific to the temperatue at which the measurements were made, in this case 338K.
The equation of rate = k[N_{2}O_{5}] is one of the simpler types of rate expressions.
To explore more complex examples, move on to the next page.